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EXTENDING COPPER TECHNOLOGY:
Thinner barriers, better performance

Ultra-thin molecular structures—known to researchers for about 20 years—can be used in a new way that could make computers and other microelectronic devices faster and more efficient.

A team headed by Ganapathiraman Ramanath, assistant professor of materials science and engineering at Rensselaer Polytechnic Institute, has for the first time, successfully used self-assembled molecular layers (SAMs) as ultra-thin barriers to keep copper from diffusing into adjacent insulating layers in microelectronics devices. SAMs are a class of materials whose molecules stand up straight and form a dense continuous layer.


“The advantage of SAMs is that, because of their size, they can be used with current copper technology as well as with future technologies such as carbon nanotube-based molecular electronics.”
—Ganapathiraman Ramanath—

This advance, reported in the April 23 issue of Applied Physics Letters, could extend copper technology by allowing cheaper fabrication of smaller, more reliable interconnect structures with more than twice the interconnect speed than would otherwise be possible.

Copper, the preferred material for interconnecting devices in a chip, easily diffuses into insulation layers that separate multilevel metal wiring. To prevent diffusion, barrier layers separate the copper from the insulation. Ramanath’s group, the first to test SAMs for barrier properties, has demonstrated that SAM layers as thin as 1.5 nanometers inhibit copper diffusion into silica.

“The advantage of SAMs is that, because of their size, they can be used with current copper technology as well as with future technologies such as carbon nanotube-based molecular electronics,” Ramanath says.

CONTACT: Theresa Bourgeois, (518) 276-2840, bourgt@rpi.edu

     
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