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Campus.News March 31, 2003

Carbon Nanotubes Prove Sensitive to the Elements

Saroj Nayak is one of the few researchers in the country studying how molecules affect the electrical conductivity of single-walled carbon nanotubes. Understanding what molecules increase or decrease nanotube conductivity is key in the development of ultra-sensitive devices that could detect the slightest traces of air-borne toxins such as anthrax or pollutants in drinking water.

 
  Go to Nayak Web site
for an animated illustration.
Nayak, assistant professor of physics, has found that exposing nanotubes to minute traces of water substantially decreases the nanotubes’ electrical current, while exposure to oxygen increases the current.

Such research could lead to better sensors in water monitors. The nanotubes in such a device, for instance, would have few electrical properties in normal drinking water. But when the sensor is exposed to a toxic element, an electrical current would trigger an alarm.

On the other hand, such a sensor could depend on a decrease of electrical current to operate. In that case, a device could shut down a water-supply system if a biological or chemical agent were present. Research is under way to study how the nanotubes react with carbon monoxide and ammonia.

“Consider that billions of nanotubes could fit inside a sensor the size of a fingertip,” Nayak says. “That and the fact the nanotube conductivity is extremely sensitive to foreign molecules makes such sensors hundreds of times more sensitive than what is currently available.”

Nayak, still perfecting the simulations, says the biggest challenge is distinguishing one molecule from another based on a nanotube’s electrical current. For example, an ammonia and a water molecule could both affect the nanotube’s electrical current the same way.

Nayak’s findings were reported in the journal of Applied Physics Letters and his research is supported by the American Chemical Society. Pulickel Ajayan, professor of materials science and engineering at Rensselaer, graduate student Yiming Zhang, and postdoctoral associate Ranjit Pati are on Nayak’s research team.

 

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