Microelectronics Research
Director’s Message
P.M. Ajayan
Yvonne Akpalu
Christin Choma
Wilfredo Colón
Shekhar Garde
Ravi Kane
Chang Ryu



Rensselaer received $300,000 in funding to evaluate a new microelectronics insulating material that has the potential to double the processing speed of microchips. The money is part of $1 million in awards to four institutions through the New York State Office of Science, Technology, and Academic Research (NYSTAR)'s Technology Transfer Incentive Program.

Rensselaer has issued a license to the Polyset Company, who is providing an additional $300,000 in funding for the project, to manufacture and market the resins, and will evaluate and optimize the materials for commercialization. This research is expected to create new markets for a material that is manufactured in New York state and add at least 100 new high-tech jobs in the next four to five years.

James Crivello, professor of chemistry and polymer faculty member at Rensselaer, developed and patented a process for making pure multifunctional epoxy siloxane resins, which are considered to be the next-generation insulating material for a range of micro- and optoelectronics applications.

"As it moves from aluminum to copper interconnects, the microelectronics industry needs new low-dielectric-constant (low-k) insulators to support its drive to produce smaller, faster devices," says Toh-Ming Lu. Lu is the Ray Palmer Baker Distinguished Professor of Physics at Rensselaer and director of Rensselaer’s Center for Advanced Interconnect Science and Technology (CAIST). He is also the principal investigator and manager of the project.

Co-PIs on the project are Shyam Murarka, The Elaine S. and Jack S. Parker Chair in Engineering, and physics professor Peter Persans.

The partnership with Polyset offers the opportunity to transfer the technology represented by one of these patents to the multibillion-dollar electronics industry.

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"Synergy," a term coined to describe the flow of combined energies, talents, and sheer strength of determination seems to describe the atmosphere at the NYS Center for Polymer Synthesis today. Our labs are alive with the concentrated efforts of student research work, from unraveling the intricacies of protein design and synthesis to using unusual materials like waste cellulose to create polymers. At the hub of these concentrated efforts are new faculty members, who individually represent some of the brightest minds in the field, and who, as a team, bring a sense of forward movement that propels all our work here.

This issue of Polymer Perspectives is dedicated to our "new" faculty members, some of them we welcomed on board in recent months, others who are already considered old-timers, but in terms of tenure are still new members of the team. They are: Yvonne Akpalu, Christin Choma, Chang Ryu, Ravi Kane, P.M. Ajayan, Shekhar Garde, and Wilfredo Colón. Please join me in welcoming them to the center.

On another positive note, celebration continues campus-wide about Rensselaer’s good fortune in receiving an anonymous donation of $360 million. This unprecedented gift represents the largest individual donation ever to a university, public or private, in the country. Announced last spring, the donation will be used, in part, to fund construction of a biotechnology and interdisciplinary research building. That facility will serve as a focal point in our efforts to create links with various departments and areas of study: nanotechnology, modeling and simulation, informatics, and more.

One of the strengths here at our center is the unusually high number of faculty making new polymers that may transform the way we live or create entirely new industries. This synthesis is the bread and butter of our work here — to make better, project-specific molecules: heavier, thinner, stronger, more photosensitive. The future implications of our research are boundless, from achieving plug-in power for fuel cells, to bio-medical applications that could prove landmarks in diagnosing and treating disease. We are poised in our work here at the center to break new ground in polymer research, and our gifted faculty members are paving the path.

We invite you to share our excitement as work at our center continues to speed along, opening new avenues of research, and ultimately, bringing us within arm’s reach of applications that will enhance people’s lives. Stay in touch for more updates.

Brian Benicewicz
Director
New York State Center for Polymer
Synthesis at Rensselaer
benice@rpi.edu

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Ajayan received his Ph.D. in materials science and engineering from Northwestern University in 1989. After three years of post-doctoral experience at NEC Corporation in Japan, he spent two years as a research scientist at the CNRS Laboratoire de Physique des Solides, Orsay in France and about a year and a half as an Alexander von Humboldt fellow at the Max-Planck-Institut fur Metallforschung in Stuttgart, Germany.

Ajayan’s research interests are mainly focused on the synthesis of nanostructures — the study of their structure and properties in relation to size and confinement. He is one of the pioneers in the field of carbon nanotubes and has demonstrated several possibilities for using these quasi one-dimensional structures as templates and molds for fabricating nanowires, composites, and novel ceramic fibers.

Major goals of Ajayan’s research include producing macro-assemblies made of nanostructures for applications, understanding growth mechanisms of nanostructures, and designing new structures and multifunctional nanocomposites.

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Prior to joining the faculty at RPI, Akpalu was a guest researcher with Eric J. Amis at the National Institute of Standards and Technology in Gaithersburg, MD. She obtained her B.A. in chemistry and physics from Smith College in 1992 and her Ph.D. in polymer science and engineering in 1998 from the University of Massachusetts at Amherst.

Akpalu will teach a new polymer science course in the fall of 2001, Polymer Structures and Interfaces, focusing on the use of light, x-ray, and neutron scattering for the study of molecular structure of the morphology of polymeric materials.

Akpalu’s research includes high-throughput online structural characterization, surface and interfacial behavior, and reactive multicomponent mixtures.

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Choma obtained her Ph.D. in biochemistry in 1990 from the University of Ottawa/National Research Council of Canada. She was awarded a Natural Sciences and Engineering Research Fellowship from the Canadian government. After that, Choma conducted postdoctoral research in protein design with William DeGrado at DuPont Pharmaceuticals in Wilmington, Delaware. Prior to joining the faculty at RPI, Choma was principal scientist of the Protein Engineering Facility, University of Groningen, the Netherlands, and research associate at the University of Pennsylvania.

Choma is focusing her research on designing new, completely synthetic catalytic proteins. Because proteins are complex polymers, designing new proteins from scratch (de novo design) is very challenging. Unlike the process of trying to re-engineer a natural protein for a novel application, Choma, in her research, has complete control over the size, shape, solubility, and activity of the designed protein catalyst. Success could mean an impact on the bioremediation of land and water contaminated by the mining, petroleum, and ore processing industries.

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Colón received his B.S. in chemistry from the University of Puerto Rico at Mayaguez in 1988 and received his Ph.D. in chemistry from Texas A&M University in 1993. After postdoctoral research as an NSF Fellow with Heinrich Roder at the Fox Chase Cancer Center, Colón joined the faculty at RPI in 1997.

His areas of research focus on molecular recognition in protein oligomerization and aggregation, protein folding, biophysical mechanism of amyloid formation, and protein folding defects in human diseases. Specifically, Colón is concentrating his research on how the proteins that comprise a human being organize themselves into a physical organism.

Colón received an NSF Early Career Award for $450,000 for a four-year grant studying the mechanism of protein folding. Subsequently he received the Presidential Early Career Award for Scientists and Engineers (PECASE)—NSF’s most prestigious award for outstanding faculty early in their professional careers. Granted in January 2000, the results of Colón’s work may have practical applications in medicine and biotechnology and could include insight into disease-causing mutations that result in "Mad Cow Disease" and Lou Gehrig’s Disease.

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Garde received his B.S. in chemical engineering from the University of Bombay in 1992 and his Ph.D. in chemical engineering from the University of Delaware in 1997. For the next two years, he performed independent research at the Los Alamos National Laboratory under a Director’s postdoctoral fellowship.

Using molecular simulation and statistical mechanical tools, Garde’s research focuses on understanding three-dimensional organization of water molecules in the vicinity of nonpolar and polar solutes and protein interfaces. He hopes to determine how this peculiar water organization induces interactions between solutes of different geometric shape and chemical nature. These water-mediated interactions provide driving forces for proteins to fold into unique three-dimensional structures that are responsible for their various functions.

At Rensselaer Garde is teaching Thermal and Fluids Engineering and Statistical Thermodynamics. His research team is also creating simulations of molecular dynamics that high school teachers can use to help illustrate difficult concepts in chemical engineering to students.

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Keeping his concentration in chemical engineering, Kane received his B.S from Stanford University in 1993 and his Ph.D. in 1998 from Massachusetts Institute of Technology. From there, Kane traveled up the Charles River to Harvard, where he spent two years as a postdoctoral fellow.

Kane has served as a teaching assistant for courses in fluid mechanics and has worked with Dow Corning Company. His research at that time focused on the development of an ASPEN model for a train of distillation columns to increase product throughput and purity.

Kane’s research at Rensselaer includes polyvalency, biosurface chemistry, biophysical studies using capillary electrophoresis and surface plasmon resonance spectroscopy, and the patterning of proteins using soft lithography.

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Ryu received both his bachelor’s and master’s degrees in chemical technology from the Seoul National University in Korea. Before moving to the United States, Ryu worked as a researcher in the polymer processing laboratory at the Korea Institute of Science and Technology.

Crossing the Pacific, Ryu moved to the Midwest to pursue his Ph.D. in chemical engineering at the University of Minnesota. During that time, Ryu also taught classes in materials energy balances and numerical analysis for chemical engineers. He graduated in 1998. Crossing the country one more time, Ryu served as a postdoctoral assistant at the University of California, Santa Barbara under the direction of professors Ed Kramer and Glenn Fredrickson.

At Rensselaer, Ryu’s research focuses on the structure and dynamics of self-assembling macromolecules. Last year, he presented his research on the self-assembly of multicolor block co-polymers at the March meeting of the American Physical Society in Minneapolis.

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NOTICE:
Beginning with next issue, Polymer Perspectiveswill be distributed via e-mail and at this web address only. Those wishing to continue their subscriptions should send an e-mail to: polymers@rpi.edu

 


Department of Chemistry
Tom Apple
Brian C. Benicewicz
James Crivello
Leonard V. Interrante
Sonja Krause
James A. Moore
Department of Materials Science and Engineering
Chan Chung
Linda Schadler
Sandy Sternstein
Department of Chemical Engineering
Georges Belfort
Steven Cramer
Jonathan Dordick
Bruce Nauman
Department of Physics
Toh-Ming Lu

 

For more information contact:
Brian C. Benicewicz
Director, The New York State Center for Polymer Synthesis
Professor, Department of Chemistry
Rensselaer Polytechnic Institute
Troy, NY 12180
Phone: 518.276.2534
Fax: 518.276.6434
E-mail: benice@rpi.edu

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