GANAPATHIRAMAN RAMANATH
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Title(s): | Professor | ||
| Department: | Materials Science and Engineering | |||
| Website: | http://www.rpi.edu/dept/materials/GR/ | |||
| Email: | ramanath[at]rpi[dot]edu | |||
| Phone: | (518) 276-6844 | |||
| Fax: | (518) 276-8554 | |||
| Postal Mail: | Rensselaer Polytechnic Institute, 110-8th Street | |||
| (111 Materials Research Center) Troy, NY 12180 |
Career Highlights
|
Professor Ramanath received his Ph.D. in Materials Science
and Engineering from the University of Illinois-Urbana in 1997.
His doctoral work won him a Materials Research Society Graduate
Student Award. He obtained his B.Tech. in Metallurgical Engineering
from the IIT, Madras, India, and his M.S. in Materials Science
and Engineering from the University of Cincinnati. He was a staff
member at Novellus Systems, CA, and a Visiting Scientist at the
Physics Department of Linköping University, Sweden, before he
joined the Rensselaer faculty as an Assistant Professor in Fall
1998. He became a tenured Associate Professor in 2003, and was
promoted to Full Professor in 2006. |
Research Areas
|
Professor Ramanath's current research interests are in the
areas of synthesis, assembly, and characterization of nanostructures
and thin films, with emphasis on exploring new materials and architectures
for fabricating future nanodevices for computing, energy generation
and management, and understanding the relationships between atomic-level
structure and chemistry, and properties. Below are synopses of
current topics being pursued in his group. Directed synthesis and assembly of nanoscopic building blocks and heterostructures The underlying theme here is to devise strategies to synthesize
nanostructures of desired dimensionalities by scalable methods,
and construct larger scale architectures in a controllable fashion
by combining chemical and/or physical guidance (molecular templating,
lithography, ion irradiation, microwave stimulation etc.) with
self-assembly. We study the molecular/atomic-level mechanisms
by utilizing a combination of multiple electron microscopy, diffraction
and spectroscopy techniques. We probe and understand the relationships
between structure, chemistry with electrical, magnetic, thermoelectric
and mechanical properties, and sensory responses. Examples of
structures being investigated include oriented nanotube architectures,
branched nanowires, nanorods, and porous networks, one- and two-dimensional
assemblies of high-coercivity nanomagnets, core-shell and branched
structures of high-figure of merit thermoelectrics, interpenetrating
proximal nanowire networks of high- and low-bandgap seminconductors
for solar cell applications. Thin film science and molecularly tailored inorganic materials and interfaces The goal of this thrust is to understand processing-stability-property
relationships and atomistic/molecular-level mechanisms of thin
film interfacial reactions and phase formation during growth (e.g.,
sputter-deposition, CVD, self-assembly) and post-deposition treatments
and relate them to key film and interfacial properties. My current
focus is on investigating the use of self-assembled molecular
nanolayers (SAMs) at the interfaces of thin films and nanostructured
assemblies as chemical isolators, physical spacers, and adhesion
enhancers. Our studies include quantitative measurements of diffusion
barrier properties, mechanical toughness, coverage, electrical
characteristics, reliability, and thermal stability of ~1-5 nm-thick
SAMs with different molecular termini and lengths at metal-dielectric
interfaces. We are integrating diffusion-inhibiting and adhesion-enhancing
molecular termini with precursors of porous materials before gelation
to create high interface integrity materials for use as low-k
dielectrics in devices. We are also exploring strategies to directly
reduce metal salts using molecular termini of SAMs incorporated
inside porous materials to obtain a high loading of nanoparticles
of controlled shapes/sizes in porous matrices to add a new component
to our directed synthesis efforts. Processing and microanalytical techniques We are interested in, and adept at, synergistically combining
and devising new multiple processing approaches for thin film/nanostructure
synthesis, and exploiting multiple microanalysis techniques to
capture key features of atomistic/molecular-level phenomena. We
use combinations of CVD, PVD, directed self-assembly (from wet-chemical
and vapor-phase fluxes), nanofabrication (e.g., lithography, etching),
ion-irradiation, microwaves, and post-deposition annealing in
vacuum/controlled gas ambients. Our growing toolbox of microanalytical
techniques include electron microscopy (conventional and high
resolution TEM, diffraction, SEM), related spatially resolved
X-ray and electron spectroscopy techniques, XRD, various spectroscopies
(e.g., RBS, XPS, AES, SIMS, EDX, IR, UV-visible), in situ electrical
measurements during deposition and annealing, 4-point bend adhesion
testing and electrical device testing (I-V, C-V, TVS, etc.). |
Selected Publications
Nanostructures synthesis, assembly and modification
- Low-temperature templateless synthesis of single-crystal bismuth telluride nanorods, A. Purkayastha, F. Lupo, S. Kim, T. Borca-Tasciuc, G. Ramanath, Adv. Mater. 18, 496-500 (2006).
- Molecularly-protected bismuth telluride nanoparticles: microemulsion synthesis, and thermoelectric transport properties, A. Purkayastha, P.G. Ganesan, A. Kumar, S.-Y. Kim, T. Borca-Tasciuc, G. Ramanath, Adv. Mater. 18, 2958-2963 (2006).
- Monodisperse high magnetic coercivity silica-capped FePt nanoparticles of tunable size, composition and thermal stability from microemulsions, Q. Yan, A. Purkayastha, T. Kim, R. Kröger, A. Bose, G. Ramanath, Adv. Mater. 18, 2569–2573 (2006).
- Electrical current-induced structural changes and chemical functionalization of carbon nanotubes, S. Agrawal, M. S. Raghuveer, R. Kröger, G. Ramanath, J. Appl. Phys. 100, 094314 (2006).
- Microwave-assisted single-step functionalization and in-situ derivatization of carbon nanotubes with gold nanoparticles, M. S. Raghuveer, S. Agrawal, N. Bishop (undergrad), G. Ramanath, Chem. Mater. 18, 1390-1393 (2006).
- Site-selective functionalization of carbon nanotubes, M.S. Raghuveer, A. Kumar, M.J. Frederick, G.P. Louie (high school teacher), P.G. Ganesan, G. Ramanath, Adv. Mater. 18, 547-552 (2006).
- Wet-chemical templateless assembly of metal nanowires from nanoparticles, T. Maddanimath, A. Kumar, J. D’Arcy-Gall, P.G. Ganesan, K. Vijayamohanan, G. Ramanath, Chem. Comm. 11, 1435-37 (2005)
- Hybrid microstructures from aligned carbon nanotubes and silica particles, S. Agrawal, A. Kumar, M.J. Frederick, G. Ramanath, Small 1 (8-9), 823-826 (2005) Coverpage feature
- Nanomachining carbon nanotubes with ion beams, M.S. Raghuveer, P.G. Ganesan, J. Mabon, J. D’Arcy-Gall, G. Ramanath, Appl. Phys. Lett. 84(22), 4484-4486 (2004)
- Exclusive horizontal growth of aligned carbon nanotubes with controlled site-selectivity and length, A. Cao, R. Baskaran, M.J. Frederick, P. M. Ajayan, K. Turner, G. Ramanath, Adv. Mater. 15(13), 1105 (2003)
- Organized assemblies of carbon nanotubes, B.Q. Wei, R. Vajtai,
Y. Jung, J. Ward, Y. Zhang, G. Ramanath, P. Ajayan, Nature 416,
495 (2002)
- Suppression of chemical and electrical instabilities in mesoporous silica films by molecular capping, A.P. Singh, D. Gandhi, E. Lipp, M. Eizenberg, G. Ramanath, J. Appl. Phys. 100, 114504 (2006)
- Surface oxide reduction and bilayer molecular assembly of a thiol terminated organosilane on Cu, P.G. Ganesan, A. Kumar, G. Ramanath, Appl. Phys. Lett. 87(1), 011905 (2005)
- Diffusion barrier properties of carboxyl- and amine-terminated molecular nanolayers, P.G. Ganesan, A.P. Singh, and G. Ramanath, Appl. Phys. Lett. 85(4), 579-581 (2004)
- Interfacial phase formation in Cu-Mg alloy films on SiO2, M.J. Frederick and G. Ramanath, J. Appl. Phys. 95(6), 3202-3205 (2004)
- Self assembled nanolayers as adhesion enhancers and diffusion barriers, G. Ramanath, G. Cui, M. Stukowski, X. Guo, P. G. Ganesan, A.V. Ellis, K. Vijayamohanan, P. Doppelt, M. Lane, Appl. Phys. Lett. 83(2), 383 (2003).
- Polyelectrolyte nanolayers as diffusion barriers for Cu metallization, P.G. Ganesan, J. Gamba, A. Ellis, R.S. Kane, G. Ramanath, Appl. Phys. Lett. 83, 3302 (2003).
- Self assembled near-zero thickness molecular layers as diffusion barriers for Cu metallization, A. Krishnamoorthy, K. Chanda, S. P. Murarka, J. G. Ryan and G. Ramanath, Appl. Phys. Lett. 78(17), 2467 (2001).
Molecularly modified thin films and interfaces
Professional Appointments
| 2006- | Professor, Materials Science and Engineering, Rensselaer Polytechnic Institute |
|
| 2003-2006 | Associate Professor, Materials Science and Engineering, Rensselaer Polytechnic Institute |
|
| 1998-2003 | Assistant Professor, Materials Science and Engineering, Rensselaer Polytechnic Institute |
|
| 2003- | Associate Editor, IEEE Transactions on Nanotechnology | |
| Summer '06 | Visiting Professor of Materials Engineering, Indian Institute of Science, Bangalore, India | |
| 2004-05 | Alexander von Humboldt Fellow, Max Planck Institute for Solids State Research, Stuttgart, Germany | |
| Summer '04 | Visiting Professor, International Center for Young Scientists, Tsukuba, Japan | |
| 1998 | Visiting Scientist, Physics Department, Linköping University, Sweden | |
| 1997-1998 | Senior Engineer, Novellus Systems, Inc., San Jose, CA | |
Professional Preparation
| University of Illinois at Urbana-Champaign | Materials Science and Engineering | Ph.D. 1997 | ||
| University of Cincinnati | Materials Science and Engineering | M.S. 1993 | ||
| Indian Institute of Technology, Madras | Metallurgical Engineering | B. Tech 1990 |
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