Ionization of water

Ionization depends on temperature, and at 25 °C, Ki for water is 10-14. At neutrality, H+ = OH¯ = 10-7. It is important to know that neutrality equates to different concentrations at temperatures other than 25 °C. Nevertheless, this is very seldom stated explicitly. More usually pH meters are calibrated with reference buffer solutions at the temperature of interest or the calibration at one temperature is converted to another by a knob on the meter. This minimizes the error of assuming that pH 7 represents neutrality regardless of the temperature.